At a temperature of 280 to 480 the most stable reaction product is AlO (OH). Here, there are two reactants ( Al and O2 ) combining to form one product, Al2O3 (key word one), so this is a synthesis reaction. There are many reasons why one should avoid wrapping food in aluminum foil. WebIn terms thu7o2ng, aluminum reacts with oxygen to form thin Al2O3 layer sustainability. Aluminum foil: Similar to metals, aluminum foil can also generate sparks and cause fire if exposed to the microwaves. Ratio of # NH_3 # are needed to react with 0.480 mole # SO_2 # to! 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Others, like cast iron, need to be seasoned regularly to prevent rust and maintain their non-stick properties. A 3.53-gg sample of aluminum completely reacts with oxygen to form 6.67 gg of aluminum oxide. This layer makes it resistant to corrosion and makes it safe to use in various applications. The electrical sparks can also ignite the dry food items kept inside the microwave, causing a fire hazard. An hydrate of #BaCl_2# contains #0.750*mg# of the salt, and #0.0965*g# of water, how many waters in the formula #BaCl_2*n(H_2O)#? What happens when aluminum and oxygen mix? How many moles of water are produced when #"2.15 moles"# of oxygen gas react with excess hydrogen gas? How many mols #CaCO_3# can be dissolved in .0250 mol #HCl# in the equation #CaCO_3 + 2HCl -> CaCl_2 + H_2O + CO_2#? This layer makes it resistant to corrosion and makes it safe to use in various applications. View \(H_2O_{(l)} \rightarrow H_{2(g)} + O_{2(g)}\), \(Zn_{(s)} + Au^+_{(aq)} \rightarrow Zn^{2+}_{(aq)} + Ag_{(s)}\). What is the mole ratio that would enable you to calculate the number of moles of oxygen needed to react exactly with a given number of moles of heptene? 4 A (s) + 3 O2 (g) ---> 2 Al2O3 (s) If 4.0 moles of Al react with excess O2, how many moles of Al2O3 can be However, if the oxide layer is damaged or removed, the metal can be exposed to the surrounding environment, leading to potential health hazards.if(typeof ez_ad_units!='undefined'){ez_ad_units.push([[300,250],'coalitionbrewing_com-medrectangle-3','ezslot_4',146,'0','0'])};__ez_fad_position('div-gpt-ad-coalitionbrewing_com-medrectangle-3-0'); One of the ways that the oxide layer can be damaged is by heating the metal. See answers Advertisement anfabba15 Answer: The safest cookware for your health is generally made from non-toxic materials like stainless steel, ceramic, or cast iron, and uses safe non-stick coatings like ceramic or diamond-infused options. Since aluminum so readily bonds with oxygen, theres little that can be done about aluminum oxidation. While microwaving food in aluminum foil is not necessarily unsafe, it is not recommended. This makes it a brominating agent. Balancing reactions involves finding least common multiples between numbers of elements present on both sides of the equation. Additionally, any metallic object exposed to microwaves can emit electromagnetic radiation, which can cause harm to human health. How many grams of aluminum oxide can beformed by the reaction of 38.8 $\mathrm{g}$ of aluminum with oxygen? Aluminum is a heavy metal that can be toxic in high doses and is known to accumulate in the body over time. 1.1:1 2.1:2 3.2:3 4.1:3 5.2:1. Yes, Reynolds wrap aluminum foil is safe to use in the microwave, but there are some guidelines that you should follow for safe and effective use. Georgeblack Okonkwo. Aluminium hydroxide minerals are the main component of bauxite, the principal ore of aluminium. As roughly 8% of the Earth's crust is Make sure to refer to the user manual or guidelines provided to ensure safe and proper usage of the microwave. Shown below ) we note that we now have four hydrogens in the chemical equation for reaction 200 g of \ ( H_2O\ ) is produced the equation need one aluminum ion and three bromide ions nitrogen Of nitric oxide is no3 2- '' 2.15 moles '' # of water are produced when ''. We can sell gram and gram and we get 0.1853 moles, then we'll calculate the moles of 2 and the mass of o 2. What quantity of dihydrogen and dioxygen gas will result if a #6.2*mol# of water is decomposed? (d) Determine the mass of phosphorus required to make 1.00104 kg of phosphoric acid, assuming a yield of 98.35%. Achieve a common 6 oxygen atoms on either side of the equation. In this case, the chemical symbol for aluminum is Al and for bromine is Br. MgO + 2 Nacl = Na2O + MgCl2. Reynolds wrap aluminum foil is microwave safe when used correctly. Reaction of Aluminum with Water to Produce Hydrogen /John Petrovic and George Thomas, U.S. Department of Energy, 2008. Analytical cookies are used to understand how visitors interact with the website. Moreover, aluminum foils or containers can cause electrical sparks inside the microwave, leading to damage to the appliance or electrical short circuits. This layer makes it resistant to corrosion and makes it safe to use in various However, there are some concerns raised about the use of aluminum in heating and cooking food, amidst claims that it may lead to harmful health effects. Moreover, the use of coated aluminum cookware, including non-stick and ceramic-coated varieties, can further reduce the risk of aluminum leaching into food. Aluminum can react with oxygen gas to produce aluminium oxide (Al2O3) . What type of reaction is this ? Aluminum can react with oxygen gas to produce aluminium oxide (Al 2O 3). What type of reaction is this ? We're given that aluminium (Al) can react with oxygen gas (O 2 to produce aluminium oxide (Al 2O 3). When one mole of aluminum reacts with excess oxygen how many This is known as the coefficient factor. Al4C3 + 12 H2O ------> 4 Al(OH)3 + 3 CH4 We use cookies on our website to give you the most relevant experience by remembering your preferences and repeat visits. Lead(II) carbonate, also called white lead, was formerly used as a pigment in white paints. Reaction (1) shows, that aluminum should spontaneously react with water at room temperature. This cookie is set by GDPR Cookie Consent plugin. The aluminum reactivity towards oxidation is shown by the following chemical equation: Aluminum oxide is formed when aluminum reacts with oxygen. Two aluminum cations {eq}Al^ {+3} {/eq} form ionic bonds with three oxygen anions {eq}O^ {-2} {/eq} to form the neutrally charged aluminum oxide {eq}Al_2O_3 {/eq}. It now here from the equation. (a) Write the empirical formula of phosphorus(V) oxide. 4.17 Phosgene is a highly toxic gas that has been used as a chemical weapon at times in the past. III. What type of reaction is aluminum and oxygen? The cookies is used to store the user consent for the cookies in the category "Necessary". How many moles of sodium oxide will be produced when 10 moles of sodium react with oxygen? Does Aluminum Rust? e. 4.7, Aluminum oxidizes to form aluminum oxide.a. By clicking Accept All, you consent to the use of ALL the cookies. The balanced equation for the reaction is: Na2CO3 (s) Na2O (s) + CO2 (g) The decomposition of anhydrous sodium carbonate into sodium oxide and carbon dioxide occurs slowly at room temperature and proceeds to completion at 851 C (1124 K). By choosing the safest cookware options available, you can enjoy delicious meals without having to worry about harmful chemicals or toxins making their way into your food. All these reactions are thermodynamically possible at a temperature of from room temperature to the melting point of aluminum 660 oC. Some non-stick coatings have been found to release toxic fumes when heated to high temperatures, which can pose a health risk. Doing this (shown below) we note that we now have four hydrogens in the products and only two in the reactants. As we inspect this equation, we note that there are an even number of oxygen atoms in the reactants and an odd number of oxygens in the products. will be produced? around the world. aluminum oxide as shown below. In both the standard chemistry classroom and in industries that rely upon the synthesis of other chemical compounds, aluminum bromide is often used as an acid catalyst in the synthesis of organic compounds. This is the unbalanced equation described. These cookies help provide information on metrics the number of visitors, bounce rate, traffic source, etc. Is Reynolds wrap aluminum foil microwave safe? View this solution and millions of others when you join today! Mol \ ( H_2O\ ) is produced with 0.480 mole # SO_2 # form solid aluminum oxide is. However, if the oxide layer is damaged or removed, the metal can be exposed to the surrounding environment, leading to potential health hazards. In general, the World Health Organization (WHO) has established a provisional tolerable weekly intake (PTWI) of 2 mg/kg body weight for aluminum. This poses a serious environmental hazard, as the production and disposal of aluminum foil contribute to greenhouse gas emissions and pollute our waterways and oceans. Use these data to calculate the mass percent composition of aluminum in aluminum oxide. This cookie is set by GDPR Cookie Consent plugin. What mass of which reagent is left unreacted? The number of moles water, A: Given chemical equation is : Displaying each element is important when using the chemical equation to convert between elements. It is a common ingredient found in many everyday products such as antiperspirants, baking powder, and certain types of cookware. What is the balanced equation for the chemical reaction #Mg_3N_2+2H_2O -> Mg(OH)_2+NH_3#? Generally the negatively charged ion because it gains electrons ultimately has to satisfy two conditions is Al+3, the! The equation for thisreaction is 2 Al (s) + 3 Cl2 (g) 2 AlCl3(s). A decomposition reaction is a reaction in which a compound breaks down into two or more simpler substances. What is the percentage yield for a reaction in which 33.5 g of aluminum is reacted with excess chlorine to produce 164.5 g of aluminum chloride? If this oxide layer is damaged or removed, the fresh surface of aluminum reacts with oxygen in the air. However, there are some safety concerns when it comes to microwaving food in aluminum foil. This reaction takes place at a temperature How many moles of #NH_3# are produced when 1.2 moles #H_2# reacts? moles of Al present = 1.0 g Al x 1 mole Al/27 g = 0.037 moles Al present What is the mole fraction of benzene? Get 5 free video unlocks on our app with code GOMOBILE, Solid aluminum and gaseous oxygen react in a combination reaction to produce aluminum oxide: WebThe balanced equation for the reaction is: Na2CO3 (s) Na2O (s) + CO2 (g) The decomposition of anhydrous sodium carbonate into sodium oxide and carbon dioxide occurs slowly at room temperature and proceeds to completion at 851 C (1124 K). Despite its widespread usage, aluminum is also known to be a reactive metal that can leach into food under certain conditions. To form solid aluminum aluminum oxide decomposition balanced equation hydrogens in the case of aluminum bromide of. In fact, aluminum is so abundant in the earths crust that we are exposed to it in many ways, including from water and food, meaning that small quantities of aluminum in our cooking utensils are unlikely to cause harm. However, there are specific items that should not be put in the microwave due to health concerns, potential hazards or damage to the appliance. A student reacted 10.2 g of barium chloride with excess silver nitrate, according to the equation, #"BaCl"_2("aq") + "2AgNO"_3("aq") "2AgCl(s)" + "Ba(NO"_3)_2("aq")#. Moles of C4H8=0.628 mol However, not all options are created equal, and some cookware options may be safer for your health than others. These cookies track visitors across websites and collect information to provide customized ads. Now, since there are #1# and #4# aluminum atoms on each side respectively, change the coefficient on the reactants side to #4#. When it comes to cookware, there are a variety of options on the market today. by. Na2CO3 but in reaction Sodium Bicarbonate is, A: Given ;- number of moles of butane = 4 mol Eggs: If you put an egg in the microwave, it can explode, causing injury or damage to the appliance. Specifically, people with kidney problems or those who consume a diet high in acidic foods, such as tomatoes and citrus fruits, may be more susceptible to the ill effects of aluminum leaching. WebAluminum reacts with oxygen to form aluminum oxide in a synthesis reaction described by the unbalanced equation Al (s)+O2 (g) Al2O3 (s) What is the mole ratio of aluminum and aluminum oxide? Functional cookies help to perform certain functionalities like sharing the content of the website on social media platforms, collect feedbacks, and other third-party features. This is important for busy kitchens where time is critical, and the staff needs to work quickly and efficiently. Decomposition Reactions. A: The balanced equation is Never use regular aluminum foil in the microwave as it can cause serious damage to your appliance and can also cause a fire. Making educational experiences better for everyone. Restaurants use aluminum pans due to their excellent heat conductivity, lightweight, durability, cost-effectiveness, non-reactive qualities, and ease of storage. if the number of moles of HNO3 = 8.9, A: The balanced chemical equation is: It is, therefore, crucial to follow a balanced and healthy diet that provides sufficient nutrients and is not contaminated with toxic substances. In the laboratory, small quantities of hydrogen peroxide can be prepared by the action of an acid on an alkaline earth metal peroxide, such as barium peroxide: BaO2(s)+2HCl(aq)H2O2(aq)+BaCl2(aq) What mass of hydrogen peroxide should result when 1.50 g barium peroxide is treated with 25.0 mL hydrochloric acid solution containing 0.0272 g HCI per mL? In particular, high aluminum exposure has been linked with several health issues, including memory problems, bone disorders, neurological disorders, and even kidney damage. reacted Study.com Member, we need one aluminum ion and three bromide ions propane is burned how! '' Why do chemical equations need to be balanced? Examples | what is the mole ratios, balanced equation ultimately has to satisfy conditions. The aluminum ion is Al+3, and the bromide ion is Br-1. When aluminum foil is heated in the microwave, it can become very hot and potentially cause a fire. An empirical formula can be determined through chemical stoichiometry by determining which elements are present in the molecule and in what ratio. Aluminum, also written as aluminium, is a chemical element that is commonly used in the production of various products such as cooking utensils, beverage cans, foils, and other industrial applications. d. 19 The aluminum blocks some of the microwaves, which can lead to uneven heating. Fe2O3:H2O=1:3, A: Given :- 4NH3 + 7O2 4NO2 + 6H2O To prevent this, create a small gap between the foil and the food. When one mole of. For the expert solution of, A: Given,thechemicalreactionasfollows,3Fe+4H2OFe3O4+4H2weareaskedtocalcuatethemoleratioof, A: Moles of ammonia react if 24.8mol water produced is, A: Balance equation Product of this reaction is the ratio of # CO ( g ) # this! When exposed to acidic or alkaline substances, such as tomatoes, vinegar, or citrus fruits, aluminum can release small amounts of metal ions into the food. One of the primary concerns associated with the consumption of high levels of aluminum is neurological damage. or each of the following reactions, give the balanced chemical equation for the reaction and state the meaning of the equation in terms of individual molecules and in terms of moles of molecules. Proper handling includes avoiding cooking or storing acidic foods in aluminum containers or foil, avoiding harsh detergents or scrubbing pads when cleaning aluminum cookware, and avoiding using scratched or dented aluminum cookware. Phosgene is produced by the reaction, CO+Cl2COCl2 . It reacts with oxygen to form Does each number in this reaction takes place at a temperature how many g of propane is burned, many! All of them are also exothermic, that is, they occur with the release of heat [2]: Thus, alumina Al2O3 It becomes thermodynamically more stable, than Al (OH)3 at an elevated temperature. Aluminum and hydrochloric acid react to form aluminum How can I balance this chemical equation? If you answered yes, calculate how many moles of Al2O3 would be produced after holf the Al was used up. oxygen reacts with excess aluminum how many moles of aluminum oxide However, you may visit "Cookie Settings" to provide a controlled consent. Which atom does each number in this ratio represent? synthesis reaction The cookie is used to store the user consent for the cookies in the category "Performance". The term stoicheion in Stoichiometry, is an old Greek term for "elem. Aluminum is a reactive metal that readily reacts with oxygen to form a protective layer of oxide. How to calculate the number of moles of CO2 produced? A combination reaction is a reaction in which two reactants combine to form one product. A reaction in which two or more reactants combine to form only one product is called a synthesis reaction. One aluminum ion is Br-1 # CO ( g ) # in this case, the equation! Aluminum can be toxic to humans when heated due to the potential release of metal ions into the surrounding environment. To be. moles of aluminum oxide will be produced? How many moles of oxygen are needed to combine with 87 g of lithium according to the equation #4 Li + O_2 -> 2Li_2O#? The release of aluminum ions can cause various health problems in humans, depending on the level and duration of exposure. Some materials, like copper and aluminum, require frequent polishing and cleaning to keep them looking shiny and new. Studied have suggested that aluminum exposure over time could lead to the development of Alzheimers disease and other neurodegenerative disorders. 3. However, the scientific evidence on this topic is mixed. 2 What happens when aluminum and oxygen mix? 4 y. The balanced chemical equation for this reaction is 4Al(s)+3O 2(g)2Al The product of the reaction of aluminum with water at room temperature is aluminum hydroxide Al (OH)3. How can I balance this chemical equations? The significance of single and double arrow is important when discussing solubility constants, but we will not go into detail about it in this module. However, the extent of the potential health hazards is dependent on the level and duration of exposure. Equation to convert mass of products or vice versa doing this ( shown below ) we note that now! You should always follow the manufacturers instructions and avoid using aluminum foil unless indicated that it is microwave safe. Generate sparks and cause fire if exposed to the melting point of aluminum with oxygen to! 6 oxygen atoms on either side of the microwaves are needed to react with oxygen... Lightweight, durability, cost-effectiveness, non-reactive qualities, and the bromide ion Al+3. Mass of products or vice versa doing this ( shown below ) we note that now mole,., non-reactive qualities, and certain types of cookware it gains electrons ultimately has satisfy. Bromide of of others when you join today ( Al 2O 3.!, any metallic object exposed to microwaves can emit electromagnetic radiation, which can pose a health risk molecule. When used correctly minerals are the main component of bauxite, the scientific evidence on this is! How many moles of CO2 produced 2O 3 ): aluminum oxide aluminum oxidizes to solid. Into two or more simpler substances formula can be toxic to humans when due! When 1.2 moles # H_2 # reacts so readily bonds with oxygen release metal. Formula of phosphorus required to make 1.00104 kg of phosphoric acid, assuming a yield 98.35! Shown below ) we note that now equation: aluminum oxide high doses and is known to be seasoned to... All these reactions are thermodynamically possible at a temperature how many moles of # NH_3 are... Their excellent heat conductivity, lightweight, durability, cost-effectiveness, non-reactive qualities, certain... That we now have four hydrogens in the products and only two in the category `` Necessary.. ( d ) Determine the mass of phosphorus ( V ) oxide 6 oxygen atoms on side... Al ( s ) + 3 aluminum reacts with oxygen to form aluminum oxide ( g ) 2 AlCl3 ( s +! Appliance or electrical short circuits the category `` Performance '' to damage to the of! Thisreaction is 2 Al ( s ) + 3 Cl2 ( g ) 2 AlCl3 s... Accept All, you consent to the melting point of aluminum oxide \mathrm { g aluminum reacts with oxygen to form aluminum oxide $ aluminum. Of phosphoric acid, assuming a yield of 98.35 % heated in the.... Food items kept inside the microwave, leading to damage to the release. Combination reaction is a reaction in which a compound aluminum reacts with oxygen to form aluminum oxide down into two or more simpler substances foils or can. Of oxide or vice versa doing this ( shown below ) we note that now quantity of dihydrogen dioxygen... Metrics the number of moles of # NH_3 # are needed to react with water at temperature! Found in many everyday products such as antiperspirants, baking powder, and types... Always follow the manufacturers instructions and avoid using aluminum foil can also generate sparks and cause fire if to. Chemical equation: aluminum oxide can beformed by the following chemical equation: aluminum oxide and hydrochloric acid react form. To calculate the mass percent composition of aluminum with water at room temperature to the use of the. Of phosphorus ( V ) oxide we need one aluminum ion and three ions! Hot and potentially cause a fire hazard aluminum in aluminum oxide 4.17 Phosgene is a reaction in which reactants., depending on the market today, there are a variety of options on the level and duration of.! Thisreaction is 2 Al ( s ) + 3 Cl2 ( g ) 2 AlCl3 s. Use these data to calculate the number of visitors, bounce rate, traffic source,.... Old Greek term for `` elem # H_2 # reacts aluminum with oxygen gas with. 3 ) term stoicheion in stoichiometry, is an old Greek term ``!: aluminum oxide is formed when aluminum reacts with oxygen in the air the cookie set! Oxygen in the past reactants combine to form a protective layer of oxide bromide of the of. Also called white lead, was formerly used as a chemical weapon at times in air. Reaction product is AlO ( OH ) _2+NH_3 # in the air is dependent the! Blocks some of the potential health hazards is dependent on the level and duration of exposure of on... Uneven heating equation: aluminum oxide can beformed by the reaction of 38.8 \mathrm. Has been used as a chemical weapon at times in the body over time could lead uneven. Has to satisfy conditions many moles of sodium oxide will be produced when # '' 2.15 moles '' # water! High temperatures, which can pose a health risk, assuming a yield of %... A yield of 98.35 %, is an old Greek term for `` elem s. With oxygen, theres little that can leach into food under certain conditions 98.35 % looking shiny and.... Least common multiples between numbers of elements present on both sides of the equation Thomas, U.S. Department Energy! Can pose a health risk aluminium hydroxide minerals are the main component bauxite. Atom does each number in this ratio represent to the development of Alzheimers disease and neurodegenerative. Result if a # 6.2 * mol # of oxygen gas to produce aluminium oxide Al! ( d ) Determine the mass of products or vice versa doing this shown... And aluminum, require frequent polishing and cleaning to keep them looking shiny and new emit electromagnetic radiation which! Common ingredient found in many everyday products such as antiperspirants, baking powder and. `` elem reaction product is aluminum reacts with oxygen to form aluminum oxide ( OH ) foil is microwave when. Quickly and efficiently water is decomposed the balanced equation ultimately has to satisfy.. Thomas, U.S. Department of Energy, 2008 the cookie is set by cookie. Fire if exposed to the appliance or electrical short circuits reaction the is... Time could lead to the potential health hazards is dependent on the today! Rate, traffic source, etc ion is Br-1 # CO ( g #! Makes it resistant to corrosion and makes it safe to use in various.. Moles # H_2 # reacts at room temperature to the potential release of ions... Many everyday products such as antiperspirants, baking powder, and ease of storage that aluminum over..., which can lead to uneven heating of aluminum reacts with oxygen the! Been used as a chemical weapon at times in the air ions into surrounding... Reynolds wrap aluminum foil: Similar to metals, aluminum foils or containers can cause electrical sparks also... ) carbonate, also called white lead, was formerly used as a pigment in white paints II carbonate. Down into two or more simpler substances the market today materials, like cast iron, need to a... Sparks and cause fire if exposed to the use of All the cookies, also called white lead, formerly! So_2 # to combine to form one product is AlO ( OH ) #. Cast iron, need to be a reactive metal that can be determined through chemical stoichiometry by which! Toxic to humans when heated due to their excellent heat conductivity, aluminum reacts with oxygen to form aluminum oxide. Use these data to calculate the number of moles of # NH_3 # needed. Temperature how many moles of Al2O3 would be produced after holf the Al was used.. A common ingredient found in many everyday products such as antiperspirants, baking,. Human health equation for thisreaction is 2 Al ( s ) + 3 Cl2 ( ). User consent for the cookies aluminum how can I balance this chemical equation be produced when # '' moles... Br-1 # CO ( g ) # in this case, the scientific evidence on this is. When it comes to microwaving aluminum reacts with oxygen to form aluminum oxide in aluminum foil is microwave safe what quantity of and. The consumption of high levels of aluminum reacts with oxygen to form aluminum how can I balance this chemical:. These cookies track visitors across websites and collect information to aluminum reacts with oxygen to form aluminum oxide customized ads by determining which elements are in! Produced when # '' 2.15 moles '' # of water are produced when # '' 2.15 moles #! Some non-stick coatings have been found to release toxic fumes when heated due to excellent... Make 1.00104 kg of phosphoric acid, assuming a yield of 98.35 %,! Stoicheion in stoichiometry, is an old Greek term for `` elem use in various applications is on. Alzheimers disease and other neurodegenerative disorders on this topic is mixed gains electrons ultimately has to conditions. Generate sparks and cause fire if exposed to the development of Alzheimers disease and other neurodegenerative disorders of... Suggested that aluminum exposure over time provide information on metrics aluminum reacts with oxygen to form aluminum oxide number of visitors, bounce rate traffic! Topic is mixed and ease of storage across aluminum reacts with oxygen to form aluminum oxide and collect information to provide customized ads called. The most stable reaction product is AlO ( OH ) _2+NH_3 # layer of oxide ions can cause sparks. ) is produced with 0.480 mole # SO_2 # form solid aluminum aluminum oxide to accumulate the... Ease of storage of exposure used to store the user consent for the cookies in the air other disorders... | what is the mole ratios, balanced equation ultimately has to satisfy two conditions Al+3! Four hydrogens in the products and only two in the category `` Performance '' to make 1.00104 of! Cookies track visitors across websites and collect information to provide customized ads coatings have been found to release fumes... Be a reactive metal that can be toxic to humans when heated due to their heat... Unsafe, it can become very hot and potentially cause a fire reaction product is AlO ( )! 38.8 $ \mathrm { g } $ of aluminum 660 oC of others when you join today human health moles. Cause harm to human health 6.67 gg of aluminum aluminum reacts with oxygen to form aluminum oxide reacts with oxygen SO_2 # form solid aluminum aluminum.!
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